Imide-based epoxy curing agent

Research & Development

High heat resistance, flexibility, low dielectric properties

Imide-based epoxy curing agent

It contributes to improving the performance of your epoxy resin.

A new imide-based epoxy curing agent have been developed by Unitika's original manufacturing process.
It solves the problems of epoxy resin used for electronic parts in the high temperature range and contributes to the improvement of the performance of your epoxy resin.

Features

  • ・Heat-resistant
    High heat resistance is achieved by introducing imide group into the epoxy curing system.
  • ・Low dielectric properties
    It is ideal for use in the electronics field.
  • ・Applicability
    It can also be applied to improve the characteristics of your existing epoxy curing system.
  • ・Flexibility
    Heat resistant type and flexible type are available.
    By using them together, ideal characteristics are expressed.

Imide group can be introduced into epoxy curing systems

By using them together,
it is possible to achieve both heat resistance and shape stability.

image of Heat resistant type

Heat resistant type

High heat resistance, high toughness (high strength), low dielectric properties
High performance was achieved with low crosslink density by introducing imide group.
High insulation (By joint study with Tokyo City University)

image of Flexible type

Flexible type

Excellent flexibility (low elastic modulus & high elongation), low dielectric properties
Shape stability of epoxy cured product (prevention of cracking, warping and peeling)
The above characteristics are achieved by introducing flexible chemical structure.

General properties

Curing agentHeat resistant typeHeat resistant type
/ Flexible type*2
Heat resistant typePN*3PN /
Heat resistant type*2,3
PropertiesAppearanceYellow powderYellow liquid
Functional group equivalentg/eq2741510104
Characteristics of cured epoxy resin *1Tensile strengthMPa966735442
Tensile elongation%91035824
Tg (DMA)22321214132128
E’ (DMA)MPa27301970327651639
Dielectric constant DK*4-3.052.912.213.082.86
Dielectric dissipation factor Df*4-0.0140.0110.0070.0330.027
CTE *510-6/℃57861632*77081
Td5*6385380314369369
  • *1 Epoxy resin : BADGE (Bisphenol A Diglycidyl Ether), Accelerator : 2-Ethyl-4-methylimidazole (2E4Mz) 0.2wt%, Mixing ratio : Epoxy resin / Curing agent = 1/1 (Functional group equivalent ratio), Curing condition : 120°C 1h → (22.5°C/h) →300°C 1h
  • *2 The ratio of the flexible type to the resin solid content was set to 15wt%.
  • *3 PN : Phenol novolac hardener
  • *4 Cavity perturbation method (5.8GHz)
  • *5 50〜100°C
  • *6 Air atmosphere
  • *7 20~50°C

< June 01, 2023 >